학술논문

Analogs of ecdysteroids with a tetrasubstituted Δ8,14-bond.
Document Type
Article
Source
Russian Journal of Organic Chemistry. May2008, Vol. 44 Issue 5, p671-674. 4p.
Subject
*ECDYSTEROIDS
*HYDROGENATION
*PHOTOCHEMISTRY
*HORMONES
*HYDROGENOLYSIS
Language
ISSN
1070-4280
Abstract
By hydrogenation of (20 R,22 R)-6α,14α,25-trihydroxy-and (20 R,22 R)-6β,14α,25-trihydroxy-2,3:20,22-bis(isopropylidenedioxy)-5α-cholest-7-enes on a catalyst (Raney nickel) the corresponding (5α,6α)-and (5β,6β)-epimers of previously unknown Δ8,14-6-hydroxy derivatives of ecdysteroids were synthesized. [ABSTRACT FROM AUTHOR]