학술논문
Crystal Structures of Two Luminescent Mononuclear and dinuclear cyclopalladated 2-(4-Ethylphenyl)pyrazine complexes.
Document Type
Article
Author
Source
Subject
*CRYSTAL structure
*LUMINESCENCE
*HYDROGEN bonding
*SINGLE crystals
*CHEMICAL synthesis
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Language
ISSN
0022-4766
Abstract
Two mononuclear and dinuclear cyclopalladated 2-(4-ethylphenyl)pyrazine (epp) complexes 2 and 3 are prepared in the bridge-splitting reactions of palladacyclic dimer 1 with PPh3 (2 ) and 1,4- bis(diphenylphosphino)butane (dppb) (3 ). Their crystal and molecular structures are determined by the single crystal X-ray analysis. C-H⋯N(Cl) hydrogen bonds and π⋯π interactions are found in the the crystals. [ABSTRACT FROM AUTHOR]