학술논문
On the Use of Ligand Field Parameters in the Study of Coordinated Water Molecules in Eu3+ Complexes.
Document Type
Article
Source
Subject
*LIGANDS (Chemistry)
*METHODOLOGY
*PHOTOCHEMISTRY
*ELECTROCHEMISTRY
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Language
ISSN
1089-5639
Abstract
A new methodology is proposed by which the number of coordinated water molecules, n, can be estimated in Eu3+ complexes. It is based on a comparison between the theoretical and experimental Stark levels, the former being calculated by assuming that n varies from 0 to 4 and predicting the so-called ligand field parameters, [inline equation] . The methodology, initially developed in the study of the Eu(pya)3·nH2O complex, has been applied successfully to β-diketonate complexes of Eu3+, for which crystallographic and luminescence data are available. [ABSTRACT FROM AUTHOR]