학술논문

Effect of mechanical depoling on piezoelectric properties of NaBiTiO- xBaTiO in the morphotropic phase boundary region.
Document Type
Article
Source
Journal of Materials Science. Feb2018, Vol. 53 Issue 3, p1672-1679. 8p. 4 Graphs.
Subject
*PIEZOELECTRIC ceramics
*MORPHOTROPIC phase boundaries
*FERROELECTRIC crystals
*TITANIUM oxides
*COUPLING reactions (Chemistry)
*CRYSTAL defects
Language
ISSN
0022-2461
Abstract
The effect of mechanical stress on the direct piezoelectric properties of pre-poled (1 − x)(NaBi)TiO- xBaTiO (NBT- xBT) in the range 4% ≤ x ≤ 13% was studied in situ using a mechanical load frame. Prior to mechanical loading, compositions near the morphotropic phase boundary (MPB, x = 6-7% BT) exhibited enhanced ferroelectric and piezoelectric properties compared to compositions further from the MPB. Specifically, the lowest ferroelectric coercive field and highest piezoelectric coefficient within this composition range occur at x = 7% BT. During mechanical compression, the MPB compositions exhibited the lowest depoling stress. The results demonstrate that, while favorable piezoelectric and ferroelectric properties can be obtained at compositions near the MPB, these compositions are also the most susceptible to the effects of mechanical depoling. Ferroelastic domain wall motion is suggested as the primary factor that may be responsible for these behaviors. [ABSTRACT FROM AUTHOR]