학술논문

Formylation of indol-1-yl acetates.
Document Type
Article
Source
Russian Journal of Organic Chemistry. Nov2017, Vol. 53 Issue 11, p1655-1659. 5p. 3 Diagrams.
Subject
*FORMYLATION
*INDOLEACETIC acid
*CARBONITRILES
*VILSMEIER reagents
*CHEMICAL reactions
Language
ISSN
1070-4280
Abstract
Preparation procedure was developed for 3-formylindole-5,6-dicarbonitriles underlain by the treatment of 1-acetoxyindole-5,6-dicarbonitriles with Vilsmeier-Haack reagent; a special feature of this reaction consisted in a replacement of the OAc group for hydrogen. A probable mechanism was assumed of the formation of 3-formylindole-5,6-dicarbonitriles. [ABSTRACT FROM AUTHOR]