학술논문

(−)/(+)-Sparteine induced chirally-active carbon nanoparticles for enantioselective separation of racemic mixtures.
Document Type
Article
Source
Chemical Communications. 6/14/2016, Vol. 52 Issue 47, p7513-7516. 4p.
Subject
*SPARTEINE
*CARBON
*DICHROISM
*ENANTIOSELECTIVE catalysis
*NANOPARTICLES
*POLARIMETRY
Language
ISSN
1359-7345
Abstract
Chiral carbon nanoparticles (CCNPs) were developed by surface passivation using the chiral ligand (−)-sparteine or (+)-sparteine (denoted (−)-SP/CNP and (+)-SP/CNP, respectively). The chirality of the prepared CCNPs was demonstrated by circular dichroism and polarimetry and employed as an enantioselective separation platform for representative racemic mixtures. [ABSTRACT FROM AUTHOR]