학술논문

Nickel-catalyzed cross-coupling of aldehydes with aryl halides via hydrazone intermediates.
Document Type
Article
Source
Chemical Communications. 2/18/2018, Vol. 54 Issue 14, p1750-1753. 4p.
Subject
*NICKEL catalysts
*ALDEHYDES
*ARYL halides
Language
ISSN
1359-7345
Abstract
Traditional cross-couplings require stoichiometric organometallic reagents. A novel nickel-catalyzed cross-coupling reaction between aldehydes and aryl halides via hydrazone intermediates has been developed, merging the Wolff–Kishner reduction and the classical cross-coupling reactions. Aromatic aldehydes, aryl iodides and aryl bromides are especially effective in this new cross-coupling chemistry. [ABSTRACT FROM AUTHOR]