학술논문
pTSA/[bmim][BF] Ionic Liquid: A Powerful Recyclable Catalytic System for the Synthesis of α-2-Deoxyglycosides.
Document Type
Article
Source
Subject
*IONIC liquids
*GLYCOSIDE synthesis
*GLYCOSYLATION
*GLYCALS
*NUCLEOPHILIC reactions
*SULFONIC acids
CATALYSTS recycling
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Language
ISSN
1022-5528
Abstract
α-2-Deoxyglycosides were synthesized in ionic liquid ([bmim]BF)by stereoselective glycosylation of endo-glycals with various o-nucleophiles in the presence of catalytic amount of pTSAin 71-95 % yield. High yields, easy recovery of the products, and reusable reaction medium (pTSA/IL couple) with consistent activity makes this protocol efficient and environmentally benign. [ABSTRACT FROM AUTHOR]