학술논문
Single-Pot Conversion of Tetrahydrofurfuryl Alcohol into Tetrahydropyran over a Ni/HZSM-5 Catalyst under Aqueous-Phase Conditions.
Document Type
Article
Source
Subject
*FURFURYL alcohol
*TETRAHYDROPYRANYL compounds
*AQUEOUS solutions
*COVALENT bonds
*BIFUNCTIONAL catalysis
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Language
ISSN
1867-3880
Abstract
Ni-based catalysts were examined in the hydrogenolysis of tetrahydrofurfuryl alcohol, resulting in the selective C−O bond cleavage to produce 1,5-pentanediol, along with 1,2,5-pentanetriol, which was detected for the first time under aqueous-phase conditions. 70 % yield to tetrahydropyran was achieved using one-pot conversion over bifunctional Ni/HZSM-5 catalysts. [ABSTRACT FROM AUTHOR]