학술논문

Probing the Connectivity and Wettability of Carbon Aerogels and Xerogels via Low-Field NMR.
Document Type
Article
Source
AIP Conference Proceedings. 2017, Vol. 1917 Issue 1, p1-5. 5p. 1 Black and White Photograph, 1 Chart, 2 Graphs.
Subject
*XEROGELS
*TORTUOSITY
*WETTING
*CHEMICAL synthesis
*CARBON compounds
*CYCLOHEXANE synthesis
*NUCLEAR magnetic resonance spectroscopy
Language
ISSN
0094-243X
Abstract
In the present work the liquid morphology, under partially saturated conditions inside two carbon aerogel and xerogel samples, was investigated using the low-field nuclear magnetic resonance (NMR) relaxometry. Information about the tortuosity of the two samples was also extracted using pulse field gradient NMR diffusometry. The molecules under investigation were water and cyclohexane. They were chosen due to their different interaction with the carbonaceous matrix. It was found a non-uniform coverage of molecules on the pore surface except for the case of cyclohexane filled carbon xerogel when the distribution was uniform. It was also observed an influence of the cyclohexane-surface interaction on the tortuosity factor characterizing the xerogel sample. [ABSTRACT FROM AUTHOR]