학술논문
A New Pyrrole Synthesis via Silver(I)-Catalyzed Cycloaddition of Vinylogous Diazoester and Nitrile.
Document Type
Article
Source
Subject
*PYRROLES
*CHEMICAL synthesis
*SILVER ions
*SILVER catalysts
*RING formation (Chemistry)
*NITRILES
*FLUORIDES
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Language
ISSN
1523-7060
Abstract
A new synthesis of di- and trisubstituted pyrroles was achieved by treating in situ generated vinylogous diazoesters and readily available nitriles with a catalytic amount of silver(I) antimony hexafluoride at room temperature. This method showcased the potential of utilizing silver(I) carbenoids in preparing heterocyclic compounds. [ABSTRACT FROM AUTHOR]