학술논문

Synthesis of 2-phenoxyl-2-oxo-1,4,2-oxazaphosphinanes from a three component reaction.
Document Type
Article
Source
Phosphorus, Sulfur & Silicon & the Related Elements. 2020, Vol. 195 Issue 5, p359-366. 8p.
Subject
*CARBONYL compounds
*HETEROCYCLIC compounds
*PHOSPHONATES
*DIPHENYL
Language
ISSN
1042-6507
Abstract
A one-pot synthetic strategy was developed for the synthesis of heterocyclic 1,4,2-oxazaphosphinanes via a three component Kabachnik-Fields reaction of 2-aminophenol, diphenyl H-phosphonate and carbonyl compounds. Through this newly developed method, 12 organophosphorus heterocycles and 2 related chrysin derivatives were synthesized with high yields. The target compounds were characterized by 1H, 31P and 13C NMR and MS. [ABSTRACT FROM AUTHOR]