학술논문

Synthesis and Characterization of New Layered Double Hydroxide-Polyolefin Film Nanocomposites with Special Optical Properties.
Document Type
Article
Source
Materials (1996-1944). 11/1/2019, Vol. 12 Issue 21, p3580. 1p. 1 Diagram, 3 Charts, 10 Graphs.
Subject
*OPTICAL properties
*LOW density polyethylene
*HYDROXIDES
*X-ray fluorescence
*LAYERED double hydroxides
*INFRARED spectroscopy
*THERMOGRAVIMETRY
Language
ISSN
1996-1944
Abstract
In this study, we have synthesized new double layered hydroxides to be incorporated to low density polyethylene thermoplastic matrix. These new composites present promising applications as materials to build greenhouses due to the enhancement of their optical properties. A characterization of the modified nanoclay has been performed by means of X-ray fluorescence (XRF), X-ray Diffraction (XRD), Thermogravimetric analysis (TGA), and Fourier-transform infrared spectroscopy (FTIR). We have prepared a series of polyolefin-based films to evaluate the effect of the addition of a whitening agent (disodium 2,2′-((1,1′-biphenyl)-4,4′-diyldivinylene)bis(benzenesulfonate)), the modified hydrotalcite-like material and a commercial dispersant. The rheological and mechanical characterization of the films have proved that the inclusion of the modified-layered double hydroxides (LDHs) do not substantially affect the processing and mechanical performance of the material. On the other hand, optical properties of the nanocomposites are improved by reducing the transmission in the UVA region. [ABSTRACT FROM AUTHOR]