학술논문
A free-base dipyrrin capable of forming extended architectures comparable to those of its metal(ii) complex counterpartsElectronic supplementary information (ESI) available: Additional experimental details, selected geometrical parameters and CIF files of LHand its dipyrromethane precursor red-LH, Ni[L]2, Zn[L]2and Cu[L]2structures. CCDC reference numbers 792154, 792155and 835356–835358. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c1ce05913k
Document Type
Article
Source
Subject
*BASES (Chemistry)
*PYRENE
*METAL complexes
*HYDROGEN bonding
*MOLECULAR structure
*COORDINATION compounds
*DIMERS
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Language
ISSN
1466-8033
Abstract
We demonstrate the involvement of an unprecedented hydrogen-bonded dipyrrin dimer in the generation of a 3-D hydrogen-bonded network which is structurally identical to the 3-D coordination networks formed with bis(dipyrrinato)metal(ii) complexes. [ABSTRACT FROM AUTHOR]