학술논문

Synthesis of Supramolecular Organogels Derived from Urea and Bisurea Derivatives of Dehydroabietylamine.
Document Type
Article
Source
Synthetic Communications. Oct2013, Vol. 43 Issue 20, p2824-2831. 8p. 1 Black and White Photograph, 1 Diagram, 1 Chart.
Subject
*CHEMICAL synthesis
*SUPRAMOLECULAR chemistry
*AMINES
*AROMATIC compounds
*SPECTROMETRY
*ISOCYANATES
Language
ISSN
0039-7911
Abstract
The gelation ability of diterpenes was investigated by applying aromatic linker steroid strategy. Four new mono (1) and bis-urea (2–4) derivatives of dehydroabietylamine (DAA) (a tricyclic diterpene amine) were synthesized on reaction of respective isocyanates with DAA and characterized through spectroscopic data. Three of these (1,2, and4) were obtained as low-molecular-weight organogelators that can form thermally reversible organogels. Supplementary materials are available for this article. Go to the publisher's online edition ofSynthetic Communications® for full experimental and spectral details. [ABSTRACT FROM AUTHOR]