학술논문

Integration of an aminopyridine derived cobalt based homogenous cocatalyst with a composite photocatalyst to promote H2 evolution from water.
Document Type
Article
Source
New Journal of Chemistry. 3/28/2021, Vol. 45 Issue 13, p5561-5567. 7p.
Subject
*PHOTOCATALYSTS
*AMINOPYRIDINES
*COBALT
*VISIBLE spectra
*ELECTRON capture
*PHOTOSENSITIZERS
Language
ISSN
1144-0546
Abstract
Inexpensive cocatalysts are promising materials to improve the performance of photocatalytic systems. However, a cocatalyst can be anchored onto a photosensitizer in certain amount and further loading can hinder the visible light by blocking the active sites of the photosensitizer. Herein, we introduce the utilization of a cobalt based homogenous cocatalyst with composite photocatalyst CdS/Ni3C. The homogenous cocatalyst did not occupy the physical space on the photosensitizer and the performance of CdS/Ni3C was significantly enhanced from 263 μmol h−1 to 750 μmol h−1. The present study showed that homogenous cocatalysts paved a way to further capture the electrons from photoexcited composite photocatalysts and have great potential to enhance the photocatalytic performance for low cost H2 evolution under visible light. [ABSTRACT FROM AUTHOR]