학술논문

Slow crossover in YbXCu{sub 4} (X=Ag, Cd, In, Mg, Tl, Zn) intermediate-valence compounds
Document Type
Journal Article
Author
Source
Physical Review B; 63; 5; Other Information: DOI: 10.1103/PhysRevB.63.054427; Othernumber: PRBMDO000063000005054427000001; 043105PRB; PBD: 1 Feb 2001
Subject
36 MATERIALS SCIENCE ATOMS
CRYSTAL FIELD
CRYSTAL STRUCTURE
ELECTRON DENSITY
FERMI GAS
FINE STRUCTURE
MAGNETIC SUSCEPTIBILITY
OCCUPATION NUMBER
SPECIFIC HEAT
Language
English
ISSN
0163-1829
Abstract
We compare the results of measurements of the magnetic susceptibility {chi}(T), the linear coefficient of specific heat {gamma}(T)=C(T)/T, and 4f occupation number n{sub f}(T) for the intermediate-valence compounds YbXCu{sub 4} (X=Ag,Cd,In,Mg,Tl,Zn) to the predictions of the Anderson impurity model, calculated in the noncrossing approximation (NCA). The crossover from the low temperature Fermi-liquid state to the high-temperature local-moment state is substantially slower in the compounds than predicted by the NCA; this corresponds to the ''protracted screening'' recently predicted for the Anderson lattice. We present results for the dynamic susceptibility, measured through neutron-scattering experiments, to show that the deviations between theory and experiment are not due to crystal-field effects, and we present x-ray-absorption fine-structure results that show the local crystal structure around the X atoms is well ordered, so that the deviations probably do not arise from Kondo disorder. The deviations may correlate with the background conduction electron density, as predicted for protracted screening.