학술논문
Reaction of MoS/sub 9//sup 2 -/ with Bis(carboxymethyl)acetylene. Crystal and molecular structure of (Ph/sub 4/P)/sub 2/Mo(S/sub 2/C/sub 2/(COOMe)/sub 2/)/sub 3/: a trigonal prismatic complex with a new dithiolene ligand
Document Type
Journal Article
Author
Source
J. Am. Chem. Soc.; (United States); 105:1
Subject
Language
English
Abstract
In this communication we report on the reaction of dimethyl 2-butynedioate (DMA) with the ((S/sub 4/)/sub 2/MoS)/sup 2 -/ anion in CH/sub 3/CN and on the crystal and molecular structure of one of the products, (Ph/sub 4/P)/sub 2/(Mo(S/sub 2/C/sub 2/(COOCH/sub 3/)/sub 2/)/sub 3/).DMF.C/sub 6/H/sub 6/ (I; DMF = dimethyl formamide).