학술논문

Oxygen isotopic composition of fissure-grown quartz, adularia, and calcite from broadlands geothermal field, New Zealand, with an appendix on quartz--K-feldspar--calcite--muscovite oxygen isotope geothermometers
Document Type
Journal Article
Author
Source
Am. J. Sci.; (United States); 275
Subject
15 GEOTHERMAL ENERGY BROADLANDS GEOTHERMAL FIELD
GEOCHEMICAL SURVEYS
CALCITE
GEOTHERMOMETRY
ISOTOPE RATIO
FELDSPARS
GEOTHERMOMETERS
MUSCOVITE
OXYGEN ISOTOPES
QUARTZ
CALIBRATION
NEW ZEALAND
ALKALINE EARTH METAL COMPOUNDS
AUSTRALASIA
CALCIUM CARBONATES
CALCIUM COMPOUNDS
CARBON COMPOUNDS
CARBONATES
CHALCOGENIDES
GEOTHERMAL FIELDS
MEASURING INSTRUMENTS
MICA
MINERALS
OXIDES
OXYGEN COMPOUNDS
SILICON COMPOUNDS
SILICON OXIDES
THERMOMETERS 150302* -- Geothermal Exploration & Exploration Technology-- Geochemical Techniques & Surveys
152004 -- Geothermal Data & Theory-- Isotope & Trace Element Studies
Language
English
Abstract
Oxygen isotope analyses of well developed, fissure-grown quartz, adularia, and calcite crystals are related to downhole temperatures and other data from the Ohaki-Broadlands geothermal field. The bore no. BR 7 profile shows how oxygen isotope analyses of geothermal minerals provide quantitative evidence on subsurface hydrology, particularly with regard to zones of boiling, and on the past stability of a geothermal system. The lower part of this profile permits correlation of a temperature of 275/sup 0/C with 10/sup 3/ ln ((/sup 18/O//sup 16/O)/sub quartz/(/sup 18/O//sup 16/O)/sub K-feldspar/) = 3.3. Based on the constraints gained from Broadlands, on the 600/sup 0/C quartz--K-feldspar fractionation from Blattner and Bird (1974), and on earlier data of O'Neil and Taylor (1967, 1969) and O'Neil, Clayton, and Mayeda (1969), quartz-feldspar, quartz-calcite, and quartz-muscovite oxygen isotope geothermometers may be calibrated independently of isotopic analyses of solutions. The corresponding new equations are 10/sup 3/ ln ..cap alpha.. (quartz--K-feldspar) = 0.82 + 0.74 10/sup 6/ K/sup -2/, 10/sup 3/ ln ..cap alpha.. (quartz-muscovite) = 1.30 + 1.27 10/sup 6/ K/sup -2/, and 10/sup 3/ ln ..cap alpha.. (quartz-calcite) = 0.37 + 0.88 10/sup 6/ K/sup -2/ (NBS-28 = 9.8/PDB = 30.36). The constant of the quartz-calcite equation depends directly on the scales of reporting used for silicates and carbonates respectively. (auth)