학술논문

Pt/CNT 전극 기반 전기화학식 센서의 전해질에 따른 황화수소 감지 특성
Hydrogen Sulfide Sensing Characteristics Depending on Electrolytes of Pt/CNT Liquid Electrochemical Sensors
Document Type
Article
Source
센서학회지 / JOURNAL OF SENSOR SCIENCE AND TECHNOLOGY. May 31, 2023 32(3):194
Subject
CNT
Electrochemical gas sensor
Working electrode
Hydrogen sulfide
Language
Korean
ISSN
1225-5475
Abstract
With the recent development of industrial technology, the problem of odor due to leakage of toxic gas discharged from industrial complexes is gradually increasing. Among them, hydrogen sulfide is a colorless representative odorous substance that can cause pain through irritation of the mucous membranes of the eyes and respiratory tract, and is a gas that can cause central nervous system paralysis and suffocation when exposed to high concentrations. Therefore, in order to improve the odor problem, research on a gas sensor capable of quickly and reliably detecting a leak of hydrogen sulfide is being actively conducted. A lot of research has been done on the existing metal oxide-based hydrogen sulfide gas sensor, but it has the disadvantage of requiring low selectivity and high temperature operating conditions. Therefore, in this study, a Pt/CNT-based electrochemical hydrogen sulfide gas sensor capable of detecting at low temperatures with high selectivity for hydrogen sulfide was developed. A working electrode capable of selectively detecting only hydrogen sulfide was fabricated by synthesizing Pt nanoparticles as a catalyst on functionalized CNT and applied to an electrochemical hydrogen sulfide gas sensor. It was confirmed that the manufactured Pt/CNT-based electrochemical hydrogen sulfide gas sensor has a current change of up to 100uA for hydrogen sulfide, and the both response time and recovery time were within 15 seconds.

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