학술논문

Charge transfer complexes of fullerene C with N,N-dimethylaniline derivatives.
Document Type
Article
Source
Russian Journal of General Chemistry. Dec2013, Vol. 83 Issue 12, p2320-2323. 4p. 2 Charts, 2 Graphs.
Subject
*CHARGE transfer
*FULLERENES
*DIMETHYLANILINE
*CHEMICAL derivatives
*ELECTRONS
Language
ISSN
1070-3632
Abstract
Charge transfer complexes of a series of p-substituted dimethylanilines with C fullerenes were studied by electron absorption spectroscopy. Energies of charge transfer bonds depend on three effects of substituents in the donor molecule (the inductive, resonance, and polarization effects) with domineering of the resonance effect. The energies are linearly proportional to the potentials of electrochemical oxidation of aniline derivatives. [ABSTRACT FROM AUTHOR]