학술논문

Growth behavior and kinetics of magnetite during magnetization roasting
Document Type
Article
Source
Journal of Industrial and Engineering Chemistry, 116(0), pp.400-410 Dec, 2022
Subject
화학공학
Language
English
ISSN
1876-794X
1226-086X
Abstract
The magnetization roasting of hematite with two particle sizes was performed to investigate the growthbehavior and kinetics of magnetite. The magnetite exhibited comparable growth trends throughout themagnetization roasting process at different roasting temperatures, and enhancing the roasting temperaturecan facilitate the growth of magnetite. The nascent magnetite nuclei appeared acicular, predominantlydeveloped along the edges and fissures of the hematite particles before progressively growinginward. Moreover, the temperature stress and magnetite formation led to the loose and porous structureof the nascent magnetite particles. The growth kinetics demonstrated that the growth process of magnetitecould be divided into induction period and growth period based on the different growth rates. For the same hematite sample, the growth rate of magnetite in the induction period was lower than thatin the growth period. The magnetization roasting of hematite with a smaller particle size may be completedin a shorter time, even if increasing the particle size of hematite can accelerate the growth rateof magnetite. The growth kinetic models were established based on the parabolic law, and the reliabilityof describing the growth process of magnetite was verified by comparing the predicted values with theexperimental values.