학술논문

A novel UiO-66-NH2/graphene oxide composite thin membrane for retarding membrane wetting in membrane distillation
Document Type
Article
Source
Journal of Industrial and Engineering Chemistry, 123(0), pp.62-71 Jul, 2023
Subject
화학공학
Language
English
ISSN
1876-794X
1226-086X
Abstract
Membrane distillation (MD) is considered an emerging desalination technology. However, the presenceof surfactants allows liquid to penetrate the membrane, resulting in membrane wetting, which hindersthe commercialization of MD. In this study, we use very few modified materials to prepare novel Janusthin membranes that immobilize modified materials (graphene oxide (GO) and UiO-66-NH2) on polytetrafluoroethylene(PTFE) hydrophobic base membranes via crosslinkers. The composite thin membraneproperties with eight different ratios and contents of GO and UiO-66-NH2 were fabricated and testedby a feed solution of sodium chloride containing a high concentration of sodium dodecyl sulfate. An optimalratio of Janus membrane with high flux without affecting the effluent water quality was obtained. The Janus membrane exhibited excellent anti-wetting properties compared to the original PTFE membrane. A desalination rate of up to 99.9% was still available even under 48 h of long-term operating conditionsby maintaining a flux of approximately 21.2 L/(m2h). The anti-wetting mechanism of thismembrane was further confirmed by the modified XDLVO model. It suggested that the novel Janus membranecould be a highly promising substitute to the MD process for the resource-based treatment ofsurfactant-containing wastewater, which played an important role in promoting its application.