학술논문

Metamorphic GaInP/GaInAs/Ge solar cells
Document Type
Conference
Source
Conference Record of the Twenty-Eighth IEEE Photovoltaic Specialists Conference - 2000 (Cat. No.00CH37036) Photovoltaic specialist conference Photovoltaic Specialists Conference, 2000. Conference Record of the Twenty-Eighth IEEE. :982-985 2000
Subject
Photonics and Electrooptics
Components, Circuits, Devices and Systems
Engineered Materials, Dielectrics and Plasmas
Power, Energy and Industry Applications
Photovoltaic cells
Photonic band gap
Gallium arsenide
Lattices
Strain measurement
X-ray diffraction
Extraterrestrial measurements
Transmission electron microscopy
History
Indium
Language
ISSN
0160-8371
Abstract
High-efficiency, metamorphic multijunction cells have been fabricated by growing GaInP/GaInAs subcells that are lattice-mismatched to an active Ge substrate, resulting in GaInP/GaInAs/Ge 3-junction (3J) cells. The efficiency dependence of this 3J cell on lattice-constant of the top two cells and on sublattice ordering in the GaInP top cell is presented. A variety of composition-graded buffers have been explored through X-ray diffraction reciprocal space mapping to measure strain in the cell layers, and transmission electron microscopy to minimize misfit and threading dislocations. Quantum efficiency is measured for metamorphic 1.3-eV Ga/sub 0.92/In/sub 0.08/As (8%-ln GaInAs) cells and 1.75-eV Ga/sub 0.43/In/sub 0.57/P cells grown on a Ge substrate, as well as for the 3J cell based on 4%-in GaInAs. Three-junction Ga/sub 0.43/In/sub 0.57/P/Ga/sub 0.92/In/sub 0.08/As/Ge cells with 0.50% lattice-mismatch to the Ge substrate are measured to have AMO efficiency of 27.3% (0.1353 W/cm/sup 2/, 28/spl deg/C), similar to high-efficiency, conventional GaInP/GaAs/Ge 3-junction cells based on the GaAs lattice constant.