학술논문

Evolution of ferromagnetic cluster in perovskite La0.88Sr0.12MnO3 nanocrystalline detected by EPR spectrum
Document Type
article
Source
Scientific Reports, Vol 14, Iss 1, Pp 1-8 (2024)
Subject
La0.88Sr0.12MnO3 nanocrystalline
Griffiths phase
EPR spectrum
Ferromagnetic clusters
Medicine
Science
Language
English
ISSN
2045-2322
Abstract
Abstract Electron paramagnetic resonance (EPR) studies were performed on La0.88Sr0.12MnO3 (LSMO) nanocrystalline together with the measurement of its magnetization. Various spectrum parameters including line width, effective g-value and double-integrated intensities have been analyzed in detail. We found nonlinear behavior occurred in the inverse susceptibility far above the Curie temperature T C, indicating short-range ferromagnetic (FM) clusters and Griffiths-like phase behavior in the paramagnetic (PM) phase. Based on the variation of EPR spectra, except for a typical PM resonance peak, an extra resonance signal was observed in the lower field region and developed as temperature decreased from 320 K to 110 K, which gave a direct evidence of the existence of FM cluster in the PM region of LSMO nanocrystalline. We proposed that the appearance of the Griffiths phase was due to the short FM correlation in the PM regime enhanced by surface spin ordering.