학술논문
Cyanogen formation during asymmetric cyanohydrin synthesisElectronic supplementary information (ESI) available: Details of chemicals and equipment, copies of spectra and details of spin trapping experiments. See DOI: 10.1039/c001703e.
Document Type
Article
Source
Subject
*ASYMMETRIC synthesis
*CYANOHYDRINS
*VANADIUM catalysts
*METAL complexes
*OXIDATION-reduction reaction
*REACTION mechanisms (Chemistry)
*CYANIDES
*ELECTRON paramagnetic resonance spectroscopy
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Language
ISSN
1359-7345
Abstract
During asymmetric cyanohydrin synthesis catalysed by vanadiumVoxo(salen) complexes, the catalysts are reduced to vanadiumIVoxo(salen) as determined by EPR spectroscopy; the reducing agent is cyanide which is oxidised to cyanogen viaa non-radical mechanism. [ABSTRACT FROM AUTHOR]