학술논문

Recovery and purification of nickel-63 from HFIR-irradiated targets
Document Type
Technical Report
Author
Source
Other Information: PBD: Jun 1993
Subject
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY NICKEL 63
ISOTOPE PRODUCTION
SCANDIUM
ION EXCHANGE
CHROMIUM
SOLVENT EXTRACTION
PURIFICATION
NICKEL 62 TARGET
HFIR REACTOR
SPECIFICATIONS
FLOWSHEETS
SEPARATION EQUIPMENT
ALUMINIUM
DISSOLUTION
IMPURITIES
TRANSITION ELEMENTS
REMOVAL
ANIONS
SCANDIUM 46
CHROMIUM 51
TOPO
SPECTROPHOTOMETRY
PHYSICAL PROPERTIES
CHEMICAL PROPERTIES
ISOTOPE RATIO
RADIOCHEMICAL ANALYSIS
EXPERIMENTAL DATA
COBALT 58
COBALT 60
IRON 59
ZINC 65
MANGANESE 54
HAFNIUM 181
TUNGSTEN 188
LEACHING 400703
RADIOISOTOPE PRODUCTION
Language
English
Abstract
The production of large quantities of high-specific-activity {sup 63}Ni (>10 Ci/g) requires both a highly enriched {sup 62}Ni target and a long irradiation period at high neutron flux. Trace impurities in the nickel and associated target materials are also activated and account for a significant fraction of the discharged activity and essentially all of the gamma activity. While most of these undesirable activation products can be removed as chloride complexes during anion exchange, chromium, present at {sup 51}Cr, and scandium, present as {sup 46}Sc, are exceptions and require additional processing to achieve the desired purity. Optimized flowsheets are discussed based upon the current development and production experience.