학술논문

Effect of chirality on the dynamics of domain walls in the molecular ferrimagnet [MnII(HL-pn)(H2O)][MnIII(CN)6] · 2H2O
Document Type
Original Paper
Source
Physics of the Solid State. April 2012 54(4):754-760
Subject
Language
English
ISSN
1063-7834
1090-6460
Abstract
The contributions from modes of switching, sliding, creep, and Debye relaxation of pinned domain walls to the low-frequency magnetic properties of the chiral and racemic molecular ferrimagnets [MnII(HL-pn)(H2O)][MnIII(CN)6] · 2H2O have been separated. It has been found that the chirality of the atomic and spin structures affects the temperatures of the transitions from the sliding mode to the creep mode and from the creep mode to the mode of Debye relaxation. In the chiral crystals, transitions to the creep and Debye relaxation modes have been observed at temperatures T = 7 and 5 K, respectively. In the racemic crystals, these transitions have been observed at temperatures T = 13 and 9 K, respectively, all other factors being equal.