학술논문

Thermally Coupled Catalytic Reactor for Steam Reforming of Methane and Liquid Hydrocarbons: Experiment and Mathematical Modeling
Document Type
Academic Journal
Source
Theoretical Foundations of Chemical Engineering. May 01, 2003 37(3):276-284
Subject
Language
English
ISSN
0040-5795
Abstract
An energy-efficient catalytic reactor for producing synthesis gas from methane and liquid hydrocarbons is proposed that is based on the coupling of an endothermic reaction (steam reforming of methane, hexane, or isooctane) and an exothermic reaction (hydrogen oxidation by atmospheric oxygen) in a single cocurrent apparatus. To describe the processes in such an apparatus, a two-dimensional two-temperature mathematical model is developed. It was revealed experimentally and by mathematical modeling that the heat- and mass-transfer coefficients of the gas flow in contact with the catalytically active wall in the exothermic reaction zone considerably affect the thermal conditions in the reactor.