학술논문
Mechanism of reaction of the hydrated electron with ozone, perbromate, and other strongly oxidizing inorganic oxocompounds
Document Type
Academic Journal
Source
Journal of Physical Chemistry A. July 1, 1999, Vol. 103 Issue 26, p5055, 6 p.
Subject
Language
ISSN
1089-5639
Abstract
Research on the encounter distance for the ultra-fast reactions of the hydrated electron with strongly oxidizing agents proposes a model to explain the mechanism of the reaction of the hydrated electron with strongly oxidizing inorganic oxo compounds. The model is based on photochemical studies of aqueous solutions of the oxyanions O3- and ClO3- that imply that solvation of the photoproduct O- precedes cage-back reactions. Experimental methodology and findings are discussed.