학술논문

Doping of selected schiff polybases and polyaniline with heteropolyacids: catalytic properties of the products
Document Type
Conference
Source
International Conference on Science and Technology of Synthetic Metals Science and Technology of Synthetic Metals, 1994. ICSM '94. International Conference on. :107-107 1994
Subject
General Topics for Engineers
Computing and Processing
Doping
Chemistry
Polymers
Materials science and technology
Ceramics
Fabrication
Spectroscopy
Paramagnetic resonance
Testing
Language
Abstract
Summary form only given. Conjugated polymers, such as polyaniline or polyimines can serve as convenient supports on which catalytically active species can be deposited. In the preparation of such catalysts the doping technique typically used for the fabrication of conducting polymers can be employed. Thus poly imine prepared via condensation of p-phenylenediamine-and terephtalic aldehyde and polyaniline were doped with 12-molybdophosphoric acid in order to obtain new catalytic systems active in alcohol conversion. These new catalysts were characterized spectroscopically (FTIR, UV/VIS, EPR, ESCA) and their catalytic activity was determined in the test reaction of isopropyl alcohol conversion.

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