학술논문
Supramolecular photochirogenesis with functional amyloid superstructures.
Document Type
Article
Author
Source
Subject
*INSULIN derivatives
*ENANTIOSELECTIVE catalysis
*FIBRONECTINS
*FIBRILLARIN
*IRRADIATION
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Language
ISSN
1359-7345
Abstract
Chiral variants of amyloid fibrils prepared by agitating acidified solutions of bovine insulin at 45 °C not only induced quasi-mirror-imaged circular dichroism spectra upon complexation with 2-anthracenecarboxylate but also gave anti-head-to-head-cyclodimers of the opposite absolute configurations upon photoirradiation. [ABSTRACT FROM AUTHOR]