학술논문
Synthesis and x-ray structural investigation of bismuth 2-methyl-8-quinolineselenolate Bi[C9 H5 (CH3 )NSe]3 .
Document Type
Article
Author
Source
Subject
*BISMUTH
*PHYSICAL & theoretical chemistry
*METHYL groups
*NATIVE element minerals
*ATOMS
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Language
ISSN
0009-3122
Abstract
Bismuth 2-methyl-8-quinolineselenolate, Bi[C9H5(CH3)NSe]3, was synthesized. X-ray analysis was used to determine the structure of this complex. The crystal chemistry of bismuth(III), antimony(III), and arsenic(III) 2-methyl-8-quinolineselenolates and 2-methyl-8-quinolinethiolates was discussed relative to the effect of going from Se to S as the ligand atoms and presence of a methyl group at C-2 of the quinoline system and unshared electron pair of the central atom in the complex. [ABSTRACT FROM AUTHOR]